Intramolecular N-coordination in ketiminoboranes.
نویسندگان
چکیده
Treatment of the imine PhC(=NSiMe3)py with Et2BOMe or BF3·Et2O afforded bicyclic ketiminoboranes and via intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of ·HCl and ·BF3 are reported as well as the dipyridyl imine derivative ·HCl.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 12 شماره
صفحات -
تاریخ انتشار 2015